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Electrical circuits force field

Electrochemical impedance spectroscopy leads to information on surface states and representative circuits of electrode/electrolyte interfaces. Here, the measurement technique involves potential modulation and the detection of phase shifts with respect to the generated current. The driving force in a microwave measurement is the microwave power, which is proportional to E2 (E = electrical microwave field). Therefore, for a microwave impedance measurement, the microwave power P has to be modulated to observe a phase shift with respect to the flux, the transmitted or reflected microwave power APIP. Phase-sensitive microwave conductivity (impedance) measurements, again provided that a reliable theory is available for combining them with an electrochemical impedance measurement, should lead to information on the kinetics of surface states and defects and the polarizability of surface states, and may lead to more reliable information on real representative circuits of electrodes. We suspect that representative electrical circuits for electrode/electrolyte interfaces may become directly determinable by combining phase-sensitive electrical and microwave conductivity measurements. However, up to now, in this early stage of development of microwave electrochemistry, only comparatively simple measurements can be evaluated. [Pg.461]

To recover the ideal case of Eq. (1.1) we would have to assume that (u ), vanishes. The analog simulation of Section III, however, will involve additive stochastic forces, which are an unavoidable characteristic of any electric circuit. It is therefore convenient to regard as a parameter the value of which will be determined so as to fit the experimental results. In the absence of the coupling with the variable Eq. (1.7) would describe the standard motion of a Brownian particle in an external potential field G(x). This potential is modulated by a fluctuating field The stochastic motion of in turn, is driven by the last equation of the set of Eq. (1.7), which is a standard Langevin equation with a white Gaussian noise defined by... [Pg.448]

A reorientation or depolarization of the domain is also effected by mechanical stress (e.g. 20... 50 N/mm for PZT). Influencing factors besides the stress magnitude are its direction and frequency as well as the kind of electrical circuit (e.g. open circuit, load or short circuit). If the electrical field induced by a force is in the polarization direction, the nonlinearities are essentially smaller than those of a generated field in the opposite direction or in the case of short circuit. [Pg.347]

If a liquid metal flows perpendicular to the magnetic field direction (Figure 3), a potential difference across the flow duct is induced in the metal coolant this causes a high electrical current flow when the potential difference is short-circuited by the electrically conducting walls. The relationship between magnetic field (B), electrical current (I), and mechanical force (F), when the I is flowing perpendicular to B,... [Pg.403]


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See also in sourсe #XX -- [ Pg.262 ]




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