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Effect of vicinal substituents

Nonadditivities of individual effects of vicinal substituents were recognized early. Dalling and Grant (100,101) reported that upheld (i.e., negative) a-ICSs of 2.5 to 3.5 occur at signals of substituted carbon atoms in 1,2-dimethylcyclohexanes if the methyl groups are in gauche orientation to each... [Pg.276]

Figure 12.64 Effects of vicinal substituents, acting as M-donors and acceptors, on in terminal alkenes. (Source ... Figure 12.64 Effects of vicinal substituents, acting as M-donors and acceptors, on in terminal alkenes. (Source ...
See other pages where Effect of vicinal substituents is mentioned: [Pg.259]    [Pg.145]   
See also in sourсe #XX -- [ Pg.39 ]



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