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Effect of cross-linking reaction

To study the effect of cross-linking reaction on relaxation prcx ess, the transition rates are modified. We note that t of many glass-forming liquids has an identical form as that of the viscosity r. The r of polymer system increases exponentially with time t near the gel point, i.e., r c exp[cXpt] with cCp being the cross-linking reaction rate. Therefore we assume that x exp[(Xp t], as a result, can be modified as... [Pg.162]

Figure 4 (a)-(c). Effect of cross-linking reaction time on the swelling ratio of genlpin-fixed CM, and CMsps/CDsps (with 0.7 wt% genlpin) at (a) pH 1.2 (b) pH 7.0 and (c) pH 12.0. Data represent the mean standard deviation, n=i. [Pg.1257]


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