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Edge-sharing bioctahedral structures

They have edge-sharing bioctahedral structures [37],... [Pg.185]

V— V Bonding. Since its congeners, Nb and Ta, as well as its neighbor Cr form numerous compounds with strong M—M bonds, similar behavior by vanadium might have been expected, but so far only a few are known. A triple bond (V—V = 2.20 A) occurs in V2(2,6-dimethoxyphenyl)4, which has an edge-sharing bioctahedral structure shown schematically in 17-B-VIII. [Pg.732]

Fig. 10 The electronic lability of the trans ligands in the D4j,-like dimer is transferred and spread out over all four coordination sites for the edge-sharing bioctahedral structure... Fig. 10 The electronic lability of the trans ligands in the D4j,-like dimer is transferred and spread out over all four coordination sites for the edge-sharing bioctahedral structure...
The dimeric molecules [W2(0)2(At-0R)2(0R)e] (R = Me, c-CeHn) have terminal 0X0 ligands trans to the bridging alkoxo gronps in an edge-shared bioctahedral structure." ... [Pg.427]

See other pages where Edge-sharing bioctahedral structures is mentioned: [Pg.401]    [Pg.333]    [Pg.156]    [Pg.244]    [Pg.1080]    [Pg.258]    [Pg.244]    [Pg.348]    [Pg.579]    [Pg.597]    [Pg.616]    [Pg.149]    [Pg.156]    [Pg.3610]    [Pg.333]    [Pg.8]    [Pg.17]    [Pg.17]    [Pg.84]    [Pg.427]    [Pg.121]   
See also in sourсe #XX -- [ Pg.247 ]



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