Dynamics of macromolecular

K. F. Mansfield, D. N. Theodoru. Interfacial structure and dynamics of macromolecular liquids A Monte Carlo simulation approach. Macromolecules 22 3143-3152, 1989. 

Pal SK, Peon J, Bagchi B, Zewail AH (2002) Biological water femtosecond dynamics of macromolecular hydration. J Phys Chem B 106(48) 12376-12395... 

A. Iniesta and J. G. de la Torre, J. Chem. Phys., 92,2015 (1990). A Second-Order Algorithm for the Simulation of the Brownian Dynamics of Macromolecular Models. 

With the increased level of understanding of the cyclization dynamics as monitored by intramolecular excimer fluorescence, it is now possible to extend this probe to the study of systems more complex than dilute solutions. One such situation involves the structure and dynamics of macromolecular complexes formed between polymeric proton donors and acceptors in aqueous solution. For example, there has been widespread interest in the complexes formed between poly(ethylene glycol) and poly(acrylic acid) or poly(methacrylic acid) in aqueous solution (34, 35). A second, complicated morphological problem is to describe the configurational behavior of polymer chains adsorbed on colloidal particles. This research has relevance to the understanding of steric stabilization. One system of particular interest is the interaction of poly(ethylene glycol) and colloidal silica (36-40). 

The Eqs. (175)-(177) reflect the change dynamics of macromolecular coil structure in solution and nonaccounting for this factor serious enough errors in estimation can be introduced. The intrinsic viscosity [rj] values, calculated according to the Eq. (10), are adduced in Table 23, from which their both qualitative and quantitative correspondence to this parameter experimental values [rj] follows (the average discrepancy of [rj] and [rj] makes up 8%). 

Sumpter BG, Noid DW, Liang GL, Wunderlich B (1994) Atomistic Dynamics of Macromolecular Crystals. Adv Polymer Sci 116 27-72. 

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