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Double bonds linked by C and P atoms

The RCM of diallylphenyl phosphane, eqn. (13), proceeds smoothly at 80°C in chlorobenzene (95% conversion in 5 h) when catalyzed by complex 1 of Ch. 3. The reaction occurs more readily than the self-metathesis of allyldiphenyl phosphane (10% conversion in 5 h). Steric hindrance evidently prevents the phosphorus atom from competing seriously with the olefinic bond for the vacant coordination position at the metal site (Leconte 1995a,b). [Pg.163]

X Substrate skeleton Product Catalyst Notes Reference [Pg.164]


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Atom bonding

Atomic bonding

Atomization by atomizer

Atoms and bonds

Atoms bonds

Bonding and double bonds

Bonds atomic

C atom

C—P link

Double links

Link atom

Linked-atom

P atom

P bonds

P-bonding

P-doubling

P—C bond

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