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Dodecanal titanocene dichloride

As a rather special case, alkyl aldehydes are reduced with titanocen dichloride to the hydrocarbons through a titanium-bonded alkenic intermediate as shown by a deuterium-labeling experiment. Thus, dodecanal was converted to dodecane in 71% yield, along with dodecan-I-ol in 15-20% yield alkyl ketones such as adamantan-2-one and dodecan-6-one afforded alcohols as the major products. No reduction occurred in the case of aryl aldehydes where alkene formation is impossible. ... [Pg.323]


See other pages where Dodecanal titanocene dichloride is mentioned: [Pg.550]    [Pg.901]   
See also in sourсe #XX -- [ Pg.323 ]

See also in sourсe #XX -- [ Pg.8 , Pg.323 ]

See also in sourсe #XX -- [ Pg.8 , Pg.323 ]




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Dodecan

Dodecanal

Dodecane

Titanocene

Titanocene dichloride

Titanocenes

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