2,6,10-Dodeca triene

SYNS l,6,10-DODECATRIEN-3-OL, 3,7,11-TRIMETHYL, ACETATE, (S-(Z))- 3,7,11-TRIMETHYL-1,6,10-DODECA-TRIEN-3-YL ACETATE... 

The progression toward Organlco s commercial production of lactam began in 1958. Initially, cyclododecatriene was epoxidized then hydrogenated to the alcohol. The alcohol was oxidized to the ketone, which was then transformed by reaction with hydroxylamine to the oxime which by Beckmann rearrangement yielded the lactam. They immediately began to work on a method to react nitrosyl chloride directly with dodeca-triene and eliminate some intermediate steps. This program eventually led to the earliest version of the commercial process in 1962. 

Cyclo- dodeca- triene- 1,5,9 Methanol (P(C,H3)3)3PdBr3 Methyl cyclo-dodeca-5,9-dienecarboxy-late-1 + dimethyl cyclo-dodecene-9-dicarb-oxylate-1,5 40 10 [448. 512]... 

Cyclo- dodeca- triene Ethanol PdClg/HCl Ethyl cyclo-dodeca-5,9-diene-carboxylate diethyl cyclo-dodecene-9-dicarboxylate 91 [509]... 

N,N,l-trimethyl-3,3-diphenylpropyl-amine N,N,l-trimetil-3,3-difenilpropilamina 3,7,ll-trimethyl-l,6,10-dodeca-trien-3-ol 3,7,ll-trimetil-l,6,10-dodecatrien-3-ol, nerolidol trimethylene trimetileno, ciclopropano trimethylene bromide bromuro de trimetileno... 

Demmarenol, 24-methylene Sd oil Diphenylamine Lf 0.013-1.17% Dodeca-trans-2-trans-6-10-trien-l-al, 4-ethyl-7-l 1-dimethyl LP ... 

The configurations of the bicyclo[6.2.2]dodeca-l(10),8.11-trienes (]6]-paracyclophanes) 12 and ent-12 were determined by correlation with the corresponding oxabicyclo[6.3.2]trideca-l(ll),8,12-trienes (3,6-hexanooxepines) (/>)-10 and (AZ)-IO of known configuration (for assign-... 

This reacts with cycloocta-1,5-diene or ewdo-dicyclopentadiene to give [Cu(diolefin)2]03S-CF3 complexes, and with cyclooctatetrene, cyclo-dodeca-l,5,9-triene, cycloocta-1,3-diene, or norbomylene to give Cu(olefin)03S-CF3 complexes cyclohepta-l,3,5-triene can replace benzene in the parent complex yielding Cu(CFgS03) J(triolefin). 

The cycloadditions of 4-mcthyl-3//-1,2,4-triazole-3,5(4//)-dione to tricyclo[5.2.2.02 6]-undeca-2,5,8-triene 37, tetracyclo[5.3.2.02,6.08 1°]dodeca-2,5,ll-triene, and -2,5-diene 39 have been examined107,115. Complete diastereoselectivity was observed only for the trienc derivatives 37 the structure of the adducts 38 was determined by X-ray. 

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