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DMTST trifluoromethanesulfonate

Frejd and co-workers utilized a different tactic for aniline cyclization by first employing a Heck-Jeffery protocol under solvent-free conditions to prepare o-amino dehydrophenylalanine derivatives from o-aminoaryl iodides with the former undergoing a spontaneous la cyclization-elimination sequence to afford 2-methoxycarbonyl indoles <06S1183>. Dimethyl(methylthio)sulfonium trifluoromethanesulfonate (DMTST) was used by the Okuma group to promote the cyclization of o-vinyl-A-p-toluenesulfonylanilide to N-tosylindole <06CL1122>. [Pg.151]

Resin bound monosaccharide 5 was glycosylated with pivaloate donor 6a in the presence of dimethyl(methylthio)trifluoromethanesulfonate (DMTST, Fig. 6). [Pg.253]

Silver trifluoromethanesulfonate, methylsilyl trifluoromethanesulfonate, dime-thylmethylthiosulfonium-trifluoromethane sulfonate (DMTST), and boron trifluoride diethyl etherate were obtained from Sigma-Aldrich. [Pg.190]

Abbreviations Ac acetyl AIBN azobisisobutyronitrile All allyl Bn benzyl Bz benzoyl ClAc chloroacetyl DAST diethylaminosulfur trifluoride DBU l,8-diazabicyclo[5.4.0]-undec-7-ene DDQ 2,3-dichloro-5,6-dicyano-/)-benzoquinone DMDO dimethyldioxirane DMTST dimethyl(methylthio)sulfonium trifluoromethanesulfonate Fmoc 9-fluorenyl-methoxycarbonyl HDTC hydrazine dithiocarboxylate IDCP iodonium di-collidine perchlorate Lev levulinoyl MBz 4-methylbenzoyl Me methyl MEK methyl ethyl ketone MP 4-methoxyphenyl NBS iV-bromosuccinimide NIS A-iodosuccinimide Pent n-pentenyl Pfp pentafluorophenyl Ph phenyl Phth phthaloyl Piv pivaloyl PMB 4-methoxybenzyl TBAF tetrabutylammonium fluoride TBDMS tcrt-butyldimethylsilyl TBDPS tert-butyldiphenylsilyl TCA trichloroacetyl TES triethylsilyl Tf trifluoromethanesulfonyl TMS trimethylsilyl Tol 4-methylphenyl Tr trityl Troc 2,2,2-trichloroethoxycarbonyl Ts tosyl. [Pg.199]

Pyruvate ketals can be synthesized [161] by direct condensation of a pyruvate ester with a diol in the presence of a Lewis acid, but this is less preferred because of the electron-withdrawing effect of the adjacent carboxylate group [162,163]. Therefore, several indirect methods for the acetalization have been introduced including condensation with pyruvate derivatives [164,165] or generation of the carboxylate group by oxidation of a suitable precursor [166,167,168,169]. A more efficient route to pyruvic acid acetals starts from silylated diols [170] or by the reaction between diols and methyl pyruvate dialkyl dithioacetal [171,172] activated by methyl triflate, dimethyl(methylthio)sulfonium trifluoromethane sulfonate (DMTST), nitroso tetraflu-oroborate (NOBF4), S02Cl2-trifluoromethanesulfonic acid, or Al-Iodosuccinimide (NIS) and trifluoromethanesulfonic acid [173] (O Scheme 24). [Pg.126]

DMTST Dimethyl(thiomethyl)sulfonium trifluoromethanesulfonate (triflate) Et Ethyl... [Pg.190]

Related Reagents. Dimethyl(methylthio)sulfonium Trifluoromethanesulfonate (DMTST) 7V-Iodosuccinimide W Iodosaccharin 1-Benzenesulfinyl Piperidine Diphenyl Sulfoxide. [Pg.224]

Alternate Name dimethyl(methylthio)sulfonium triflate, dime-thylthiomethyl sulfonium trifluoromethanesulfonate, DMTST. [Pg.225]

Immediately after work-up the acetals were treated with dimethyl(methylthio)-sulfonium trifluoromethanesulfonate (DMTST) in CH2CI2 to give P-o-fructofur-anoside derivatives 19, both in 11% yield. [Pg.453]


See other pages where DMTST trifluoromethanesulfonate is mentioned: [Pg.359]    [Pg.126]    [Pg.135]    [Pg.150]    [Pg.517]    [Pg.784]    [Pg.162]    [Pg.209]    [Pg.353]    [Pg.344]    [Pg.422]    [Pg.150]    [Pg.517]    [Pg.301]    [Pg.71]    [Pg.210]    [Pg.227]    [Pg.301]    [Pg.126]    [Pg.349]   


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