Dithiocarbamates cyclopentadienyl compounds

A cyclometallated azobenzene eomplex 91 was identified as a new class of highly efficient photorefractive materials.Gyclopalladated azobenzenes with N,0 chelating ligands and cyclic voltammetric studies were reported.Mesomorphic materials exhibiting a nematic phase were derived from a cyclopalladated azo compound.Mesogenic cyclopentadienyl cyclopalladated azobenzene eomplexes were also made. " Reactions of cyclopalladated azobenzenes were studied with xanthates and dithiocarbamates yielding ternary complexes. " The products were studied electroehemically. 

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