Dithioacetals reaction with allylsilanes

Apart from the tandem metathesis/carbonyl o[efination reaction mediated by the Tebbe reagent (Section 3.2.4.2), few examples of the use of stoichiometric amounts of Schrock-type carbene complexes have been reported. A stoichiometric variant of cross metathesis has been described by Takeda in 1998 [634]. Titanium carbene complexes, generated in situ from dithioacetals, Cp2TiCl2, magnesium, and triethylphosphite (see Experimental Procedures 3.2.2 and 3.2.6), were found to undergo stoichiometric cross-metathesis reactions with allylsilanes [634]. The scope of this reaction remains to be explored. 

Desulfurative silylation. Dithioacetals are converted to alkylsilanes on reaction with Cp2Ti[P(OEt)3]2 and EtjSiH. Allylsilanes are produced from p,y-unsaturated dithioacetals or l,3-bis(phenylthio)-l-alkenes. Germanes and stannanes are similarly obtained. 

Allylstannanes are much better nucleophiles for dithioacetals than allylsilanes, and dimethyl(methyl-thio)sulfonium fluoroborate is a particularly good catalyst in this reaction. The reaction has been used tellingly in a macrocyclization (Scheme 56). ° Monothioacetals also react with allylstannanes, with cleavage of either the carbon-oxygen or the carbon-sulfur bond, depending upon the choice of Lewis acid (Scheme 57).Sugar thioacetals react in the same way (Scheme 58), but with the opposite anomeric stereoselectivity from that of the corresponding radical chain substitution. ... 

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