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1.4- Dithiin 1,1-dioxide, 1,5-diphenyl

Several heterocyclic sulfur compounds have been shown to function as C2S sources in this type of thiophene synthesis. Thus 2,5-diphenyl- 1,4-dithiin 1,1-dioxide (255a) condenses... [Pg.896]

On the other hand, the photochemical behavior of 2,5-diphenyl-1,4-dithiin 1,1-dioxides (34) is remarkably different from that of the corresponding sulfoxides. Thus, irradiation of derivatives (34) gave the thiophenes (24) and (30), but in very low yields (Equation (3)) <83CL6i>. [Pg.456]

Althiophene 1,1-dioxide, which was reported years ago,118 has recently been reinvestigated,125,126 It was found that the anti head-to-head (119) and anti head-to-tail (120) isomers are formed in a ratio of 2.7. This dimerization was proposed to occur via attack of a molecule in the excited triplet state (Er SO kcal/mol) on another molecule in the ground state. The preferential formation of isomer 119 was attributed to a better stabilization of the more polar transition state in the formation of 119 relative to 120 in view of the observed effect of the polarity of the solvent on the ratio of 119 to 120. Similar dimerizations have been reported for 2-nitrobenzo-l,4-dithiin (121)127 and 1,1-dimethyl-2,5-diphenyl-l-silacyclopenta-2,4-diene (111).128 Other heterocycles that dimerize via (2 + 2)-cycloaddition, either upon direct or upon sensitized irradiation, are l/f-dibenzo[6,/l-azepine derivatives (122),129 vinylene carbonates (123),u,no and 1,3-substituted imidazolin-2-ones (124).,3, ,2... [Pg.287]

The reaction of benzyne (from anthranilic acid) with 2,5-diphenyl-1,4-dithiin 1,1-dioxide (228) follows the course outlined in Scheme 21 to give... [Pg.223]


See other pages where 1.4- Dithiin 1,1-dioxide, 1,5-diphenyl is mentioned: [Pg.615]    [Pg.960]    [Pg.967]    [Pg.615]    [Pg.960]    [Pg.967]    [Pg.81]    [Pg.615]    [Pg.615]   


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