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Dithiadiazolyl reactivity

Such important differences in reactivity have been rationalized using MO/ionization potential considerations [92JCS(D)859 93JCS(D)1499], With both NC.CN and [C(CN)3], an important step in the reaction pathway would appear to be an electrostatic interaction between SNS+ and the heterocyclic nitrogen in the intermediate 1,3,2,4-dithiadiazolyl/lium (bound to carbon), leading to (i) modification of orbital energies and (ii) an asynchronous cycloaddition mechanism (see Section XII.B). [Pg.228]

Sec. XXIII.G] DITHIADIAZOLYLIUM AND DITHIADIAZOLYL RINGS 235 G. Reactivity of Multi-1,3,2,4-dithiadiazolyl Radicals... [Pg.235]

See other pages where Dithiadiazolyl reactivity is mentioned: [Pg.219]    [Pg.220]    [Pg.138]    [Pg.139]    [Pg.139]    [Pg.139]    [Pg.140]    [Pg.189]    [Pg.216]    [Pg.216]    [Pg.218]   
See also in sourсe #XX -- [ Pg.743 ]

See also in sourсe #XX -- [ Pg.743 ]



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1,2,3,5-Dithiadiazolyls

Reactivity of 1,3,2,4-Dithiadiazolyls

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