Dissolution, theory

C.J. Mcneil, D. Athey, M. Ball, W.O. Ho, S. Krause, R.D. Armstrong, J.D. Wright, and K. Rawson, Electrochemical sensors based on impedance measurement of enzyme-catalyzed polymer dissolution theory and applications. Anal. Chem. 67, 3928-3935 (1995). 

Craw, D., Falconer, D. and Youngson, J.H. (2003) Environmental arsenopyrite stability and dissolution theory, experiment, and field observations. Chemical Geology, 199(1-2), 71-82. 

Dissolution Theory, Methodology, and Testing, edited by Anthony Palmieri HI. 

Palmieri A. 2007. Dissolution theory, methodology, and testing. Hockessin, DE Dissolution Technologies. 

Murphy, W.M. 1988. Dislocations and feldspar dissolution Theory and experimental data. Chem. Geology 70 163. 

It was found that the second-order rate law provided an excellent fit to each set of experimental data (Fig. 34a). Moreover, the normalized rate constants derived, log K2 = -0.3 a = 5 /xm), 0.1 (a = 12.5 /cm), and 0.4 (a = 25 /xm), yielded a consistent rate constant, k2lca"Ci = 0.016 cm s-1. In contrast, the first-order dissolution theory did not provide a good description of any of the sets of experimental data, and even the most consistent fits of this model did not yield a constant value of kJc%C[- These results thus reemphasize the ability of SECM to distinguish between candidate dissolution rate laws. 

Figure 2.32 Process zones next to mineral surface according to diffuse-kinetic dissolution theory...

Macpherson JV, Unwin PR (1996) Scanning electrochemical microscope-induced dissolution theory and experiment for silver chloride dissolution kinetics in aqueous solution without supporting electrolyte. J Phys Chem 100(50) 19475-19483. doi 10.1021/jp9614862... 

Palmieri, A. Ill, (ed) (2007) Dissolution Theory, Methodology, and Testing, Dissolution Technologies, Inc., Hockessin,... 

McGeouch, C. A., Edwards, M. A., Mbogoro, M., Parkinson, C., Unwin, P. R. Scanning electrochemical microscopy as a quantitative probe of acid-induced dissolution Theory and application to dental enamel. Anal. Chem. 2010, 82, 9233. 

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