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Dissociation energy oxidation states

Comparison of Dissociation Energies of Fluorides in Different Oxidation States... [Pg.55]

High-valent oxo-complexes, isolated or in situ-generated, interact most often with electron-rich n -systems 1 or suitable C-H bonds with low bond dissociation energy (BDE) in substrates 3 (Fig. 2). These reactions may occur concerted via transition states 1A or 3A leading to epoxides 2 or alcohols 4. On the other hand, a number of epoxidation reactions, such as the Jacobsen-Katsuki epoxidation, is known to proceed by a stepwise pathway via transition state IB to radical intermediate 1C [39]. Similarly, hydrocarbon oxidation to 4 can proceed by a hydrogen abstraction/S ... [Pg.124]

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See also in sourсe #XX -- [ Pg.973 ]



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Dissociations, oxides

Dissociative state

Oxidation dissociated

Oxides dissociation energy

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