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Interaction spaces dispersed systems

The effect of an applied pressure on the UCFT has been investigated for polymer particles that are sterically stabilized by polyisobutylene and dispersed in 2-methy1-butane. It was observed that the UCFT was shifted to a higher temperature as the hydrostatic pressure applied to the system increased. There was also a qualitative correlation between the UCFT as a function of applied pressure and the 6 conditions of PIB + 2-methylbutane in (P,T) space. These results can be rationalized by considering the effect of pressure on the free volume dissimilarity contribution to the free energy of close approach of interacting particles. Application of corresponding states concepts to the theory of steric stabilization enables a qualitative prediction of the observed stability behaviour as a function of temperature and pressure. [Pg.317]


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See also in sourсe #XX -- [ Pg.4 , Pg.5 , Pg.6 ]




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Disperse systems

Dispersed systems

Dispersed systems, dispersions

Dispersion interaction

Dispersive interactions

Dispersive interactions interaction

Dispersive systems

Interacting system

Interaction spaces

Interaction system

Space systems

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