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Disilenes triplet state

FIGURE 24. Transition state structure for rc-bond rotation and equilibrium triplet structure (in parentheses) of disilene at MCSCF/3-21G. Bond lengths are in A, bond angles in deg. (j> is the flap angle between the Si-Si bond and the SiH2 plane147. [Pg.133]

Two singlet silylenes dimerize to give a ground-state disilene with a substantial barrier via the least-motion path and without a barrier via the non-least-motion path. On the other hand, two triplet silylenes dimerize to give adiabatically an excited state of disilene. [Pg.187]

See other pages where Disilenes triplet state is mentioned: [Pg.413]    [Pg.20]    [Pg.131]    [Pg.1177]    [Pg.397]    [Pg.140]    [Pg.154]    [Pg.156]    [Pg.130]    [Pg.176]    [Pg.563]    [Pg.1157]    [Pg.1177]   
See also in sourсe #XX -- [ Pg.131 ]



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