Disilane, hexachloro

Inverted names are used only for derivatives of silanes (as Silane, dibromo- and Disilane, hexachloro-), germanes, phosphine, and the like, but not for the few organic compounds. For the nomenclature of some of these and other classes of compounds, see the heading Nomenclature. 

Bis(trichlorosilyl)nickel(II) complex 4, having an r/ -arene hgand,is prepared by reaction of hexachloro disilane with highly reactive, vaporized nickel in the presence of toluene (Eq. 2) [12]. Worthy of note is that the arene ligand is displaced by three molecules of carbon monoxide to give 5 [13]. 

Preparation.1 The reagent (1) is prepared by the reaction of hexachloro-disilane and a mixture of trimethyl orthoformate and methanol ... 

Sulfur Diimide Reduction. iV-Trichlorosilyldiaininosulfanes were prepared upon treatment of sulfur diimides with hexachloro-disilane (eq 9). Likewise, the corresponding IV-dichloromethyl-silyldiaminosulfanes resulted by substituting 1,2-dimethyl-1,1,2,2-tetrachlorodisilane for hexachlorodisilane. 

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