Dipole-bound anion, confined

Electron structure of a dipole-bound anion confined in a... 

Electron structure of a dipole-bound anion confined in a spherical box. Addendum to Electron structure of a dipole-bound anion in a spherical box The case of a finite dipole... 

S. Ronen, Phys. Rev. A, 68,012106 1-7 (2003). Electron Structure of a Dipole-Bound Anion Confined in a Spherical Box. 

A possible isomerization pathway for the = 6 cluster has been proposed on the basis of the quantum chemical calculations of Conbariza et al. [59] and Kim et al. [33]. In the predicted most stable structure for the ground state [59], the 1 ion lies on the surface of a V-shaped solvent network. It has been assumed that the initially excited state has a similar geometry, in which the excess electron is weakly bound by the net dipole moment of the solvent network. The supposed form after isomerization resembles the stable half-cage structure for the water hexamer anion [33], in which the excess electron is confined by dangling hydrogens of waters. 

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