Phospha-1,2-dioxetanes

CHEMILUMINESCENCE INVOLVING THE PHOSPHORUS CHEMISTRY. PHOSPHA-l,2-DIOXETANES AS THE MOST LIKELY HIGH-ENERGY INTERMEDIATES IN AUTOXIDATION OF PHOSPHONATE CARBANION... 

Consequently, phospha-l,2-dioxetanes are the only reasonable intermediates that produce the excited carbonyl fragments and simultaneously satisfy the experimental results in the present study. In this study, the substituent effect on the ring closure step in the oxy-Wittig type reaction was revealed by chemiluminescence decay. The promotion of the ring formation results in the... 

Akasaka T, Sato R, Ando W. Oxidation of phosphazine by singlet oxygen. High-field P NMR spectroscopic studies of 3-phospha-l,2-dioxa-4,5-diazine and phospha-l,2-dioxetane. J Am Chem Soc 1985 107 5539-40. 

Motoyoshiya J, Isono Y, Hayashi S, Kanzaki Y, Hayashi S, Chemiluminescent oxidation of phosphonates Phospha-l,2-dioxetanes as possible intermediates. Tetrahedron Lett 1994 35 5875-78. 

Motoyoshiya J, Ikeda T, Tsuboi S, Kusaura T, Takeuchi Y, Hayashi S, Yoshioka S, Takaguchi Y, Aoyama H. Chemiluminescence in autoxidation of phosphonate carbanions. Phospha-l,2-dioxetanes as the most likely high-energy intermediates. J Org Chem 2003 68 5950-5. 

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