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Dinitrogen bond cleavage reaction

Though carbon-nitrogen bond cleavage reaction is less explored, allylic C-N bond can be cleaved by low valent late transition metal complexes. Treatment of (/x-dinitrogen or carbon dioxide)nickel(O) complexes with allylammonium... [Pg.167]

The photochemical reaction of Re2(CO)io with PMePhg seems to fit into this two-equilibrium scheme fairly well, and so represents a recently discovered example of substitution at M2(CO)io without metal-metal bond cleavage. Dinitrogen tetroxide reacts with Re2(CO)io to cleave the metal-metal bond and give ultimately Re(N03)(C0)5, by the following sequence ... [Pg.263]

Various explanations have been given such as stepwise cleavage of the two C-N bonds with concerted backside displacement of the nitrogen molecule by the carbon radical and, intriguingly, conservation of momentum upon loss of dinitrogen that results in the double inversion product. This latter explanation has been pursued by Carpenter who has championed non-statistical dynamics as an explanation for many stereochemical pathways in thermal reactions. ... [Pg.68]


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See also in sourсe #XX -- [ Pg.269 ]




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