Dimorphecolic acid

CH3 (CH2)4CH=CHCH=CHCH(0H) (CH2)7C00H Dimorphecolic acid (9-OH10fl2c-18 2)... 

Dimorphecolic acid is one of the major fatty acids in Dimorphotheca sinuata seeds. Two complementary DNAs (cDNAs) for divergent FAD2 enzymes were isolated from developing seeds by EST sequencing and homology searches. One codes for an oleate desaturase, which introduces a trans double bond at the A-12 position of oleic acid, while the second encodes an enzyme that can convert the... 

Gaboon EB, Kinney AJ. (2004) Dimorphecolic acid is synthesized by the coordinate activities of two divergent deltal2-oleic acid desaturases. J Biol Chem 279 12495-12502. 

The relative and absolute configuration of 35,125-dihydroxypalmitic acid, a constituent of the Ipomea operculata M. resin, was confirmed by synthesis starting with dimethyl L-malate (35). An efficient synfliesis of (55)-hydroxy-20 4(6 ,8Z,l 1Z,14Z) was accomplished by the coupling of two readily accessible synthons, methyl (55)-hydroxy-7-iodo-heptanoate and 4Z,7Z- tridecadien-l-yne (36). A highly stereoselective synthesis of P-dimorphecolic acid, (95)-hydroxy-18 2(10.E,12 ), has been reported the synthesis features a diastereoselective reduction of a keto intermediate [4] in which the tricarbonyliron lactone tether induces a 1,5-transfer of chirality followed by a stereoselective decarboxylation to create all of the stereochemical ele-... 

Ley, S.V., and G. Meek, Synthesis of P-Dimorphecolic Acid Exploiting Highly Stereoselective Reduction of a Side-Chain Carbonyl Group in a it-Allyltricarbonyl Iron Lactone Complex, J. Chem. Soc. Perkin Trans. I, 1125-1130 (1997). 

Distribution Coefficients (fO and Separation Factors for Common Fatly Acid Methyl Esters (CFM), Dimorphecolic Acid Methyl Ester, and Methyl 9-Oxo-10,12 f,f octadecanoate ... 

Parameters for Countercurrent Separation of Dimorphecolic Acid Methyl Ester from Common Fatty Add Methyl Esters (CFM) Using Some Aqueous Methanol/Hexane Systems... 

Tassignon, P.S.G., P. de Waard, T. de Rijk, H. Toumois, D. de Wit, and L. de Buyck, An Efficient Coimtercurrent Distribution Method for the Large-Scale Isolation of Dimorphecolic Acid Methyl Ester, Chem. Phys. Lipids 71 187-196 (1994). 

Constit. of the seed fat of Dimorphotheca aurantiaca. Me ester [a] H-5 (c, 5.0 in CHCI3). S)ilOE,12Z)-form [10075-11-3] a-Dimorphecolic acid... 

Enantiomerically pure (9/ )-HSA can be obtained from Dimorphoteca sinuata L. seed oil, a source of 10( ),12( )-(S)-9-hydroxyoctadecadienoic acid (dimorphecolic acid). [57] After transmethylation of the seed oil, followed by hydrogenation and hydrolysis, (9/ )-HSA can be obtained and the enantiomer with opposite configuration can be synthesized through stereospecific inversion of the chiral center. [55]... 

Dimeric flavonoids, Y3 4,4 -dimethoxydalbergione, Y4 A/, y-dimethylalloisoleucine, A29 Dimorphecolic acid, A7 Dimyristoylcephalin, A15 Dimyristoyllecithin, A15 Dinoseb, A49 DIOP, A24 Diosbulbins, T13 ... 

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