Dimethyl phosphite platinum complex

This procedure is similar to that used for the synthesis of bis(dimethyl phosphito-P)[ethylenebis(diphenylphosphine)]platinum(Il).8 To a solution of bis(dimethyl hydrogen phosphite-i>)bis(dimethyl phosphito- )platinum(II) (0.976 g, 1.5 mmole) in benzene (50 mL) is added o-phenylenebis(dimethylarsine) 9 (0.441 g, 1.5 mmole). The solution is heated at reflux with stirring for 1 hour and then allowed to cool to room temperature. The colorless compound precipitates and is collected by suction filtration on a medium-porosity fritted glass. The complex is washed with benzene (two 5-mL portions) and then... [Pg.100]

CsHuN, Ethanamine, A-ethyl-A-methyl-tungsten complex, 26 40, 42 C6HF5, Benzene, pentafluoro-gold complexes, 26 86-90 C H4I2, Benzene, 1,2-diido-iridium complex, 26 125 CJT, Phenyl platinum complex, 26 136 C,H,N, Pyridine osmium complex, 26 291 OHtS, Benzenethiol osmium complex, 26 304 QH7P, Phosphine, phenyl-cobalt-iron complex, 26 353 QH 1-Butyne, 3,3-dimethyl-mercury-molybdenum-ruthenium complex, 26 329-335 C6H 4P, Phosphine, triethyl-platinum complex, 26 126 platinum complexes, 26 135-140 CsHisPO, Triethyl phosphite iron complex, 26 61... [Pg.414]

Big Chemical Encyclopedia