4.4- Dimethyl-3-hexanone

See Peroxyacetic acid 5-(4 -Chlorophenyl)-2,2-dimethyl-3-hexanone See other ORGANIC ACIDS... 

Bis((9-salicylidenaminopropylaziridine)iron(III) perchlorate, 3853 Bis(tetramethyIdiphosphane disulfide)cadmium perchlorate, 3102 Carbonyl-bis(triphenylphosphine)iridium-silver diperchlorate, 3898 5-p-Chlorophenyl-2,2-dimethyl-3-hexanone, 3664... 

Non-enolizable aliphatic ketones are cleaved analogously. For example, pivalamide and isobutane are formed in good yield from hexamethylacetone (2,2,4,4-tetramethyl-3-pentanone). Most unsymmetrically substituted ketones afford the four possible products (2 amides and 2 hydrocarbons), but often in unequal amounts, e.g., pivalamide and 2,2-diethylbutyramide in 5 1 proportions from 4,4-diethyl-2,2-dimethyl-3-hexanone. Hexaalkyl-substituted acetone derivatives containing branched alkyl groups generally do not react. 

The data refers to one of the monohydrogenated products (5-hydroxy-2,2-dimethyl-3-hexanone). 

What is the product formed when 2,2-dimethyl 3-hexanone reacts with peroxyacetic acid ... 

IX-D-18. Photodecomposition of 2,2-Dimethyl-3-Hexanone [n-Propyl ferf-Butyl Ketone, CH3CH2CH2C(0)C(CH3)3]... 

Photodecomposition of 2,2-dimethyl-3-hexanone pathways are similar to those of other ketones (Calvert et al., 2008) ... 

Styrene, the most efficient quencher of triplet excited states of carbonyl compounds among a great variety of olefins employed by Ausloos and Rebbert (1964), gave no detectable influence on the ethene and carbon monoxide quantum yields when 20.1 Torr was added to 19.9 Torr of 2,2-dimethyl-3-hexanone (Nicol and Calvert, 1967). However, an almost quantitative removal of radical products of 1-propyl and 2-methyl-2-propyl radicals resulted. Since 4>co was unaffected by styrene addition, the radical... 

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