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Dilithium tetrachlorocuprate Grignard reagents

Organometallic Reagents. The major product of the Dilithium Tetrachlorocuprate(II)- or Copper(I) /odide-catalyzed Grignard reaction in THF or ether at low temperature arises from epoxide opening rather than from direct tosylate displacement (Table... [Pg.351]

On the other hand, bromoalkanes react with saturated or ethylenic Grignard reagents in tetrahydrofuran in the presence of a suitable catalyst (dilithium tetrachlorocuprate 8-19) ... [Pg.225]

The dilithium tetrachlorocuprate (Li2CuCl4)-catalyzed alkylation of a,ct)-dihalides with Grignard reagents allows simple halopolycarbon homologation of organic structures (Friedman and Shani, 1974). The reaction is... [Pg.112]


See other pages where Dilithium tetrachlorocuprate Grignard reagents is mentioned: [Pg.34]    [Pg.119]    [Pg.244]    [Pg.482]    [Pg.138]    [Pg.77]    [Pg.824]    [Pg.147]   
See also in sourсe #XX -- [ Pg.3 , Pg.244 ]

See also in sourсe #XX -- [ Pg.244 ]

See also in sourсe #XX -- [ Pg.3 , Pg.244 ]




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Dilithium tetrachlorocuprate

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