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Dihydrogen and Hydrides

Pure rotational transitions of symmetrical diatomic molecules like dihydrogen are forbidden in infrared spectroscopy by the dipole selection rule but are active in Raman spectroscopy because they are anisotropically polarisable. They are in principle observable in INS although the scattering is weak except for dihydrogen. These rotational transitions offer the prospect of probing the local environment of the dihydrogen molecule, as we shall see in this chapter. [Pg.219]

The Extraordinary Dynamic Behavior and Reactivity of Dihydrogen and Hydride in the Coordination Sphere ofTransition Metals... [Pg.603]

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Dynamics of Dihydrogen-Hydride Ligand Systems Hydrogen Rotation, Exchange, and Quantum-Mechanical Effects

Hydride and Dihydrogen Complexes

Hydride and Dihydrogen Ligands

Hydrides and Dihydrogen Activation

Hydrides, Hydrogen Bonding and Dihydrogen Activation