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Dichloromethyl disulfide

Reactions of mercaptans with thiophosgene Dichloromethyl disulfides Thiophilic addition... [Pg.148]

N NaOH added at 0-5 during 15 min. to a soln. of / r/-butylmercaptan and thiophosgene in benzene with stirring, which is continued 2 hrs. dichloromethyl tert-butyl disulfide. Y 90%. Also with AICI3 or CF3COOH, f. e. and formation of dithiochloroformic acid esters, C1C(S)SR, s. N. H. Nilsson, Soc. Perkin I 1974, 1308. [Pg.148]

The dichloromethyl alkyl ether is generally added to a solution or suspension of the aromatic substrate and the catalyst (TiCU, SnCU, SnBr4, FeCIs or AICI3) in methylene chloride, n-hexane or carbon disulfide. Gross, Rieche and Matthey prepared phenolic aldehydes in good yields using this method. [Pg.12]


See other pages where Dichloromethyl disulfide is mentioned: [Pg.449]    [Pg.449]    [Pg.277]    [Pg.545]    [Pg.275]    [Pg.288]    [Pg.449]    [Pg.449]    [Pg.277]    [Pg.545]    [Pg.275]    [Pg.288]    [Pg.1440]    [Pg.1507]    [Pg.1490]    [Pg.1440]    [Pg.889]    [Pg.889]    [Pg.1440]    [Pg.893]    [Pg.257]   
See also in sourсe #XX -- [ Pg.21 ]

See also in sourсe #XX -- [ Pg.21 ]




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1,1 -dichloromethyl

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