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Diazido-l,2,4,5-tetrazines

This procedure is also efficient for the synthesis of other fused tetrazoles, such as ethyl l,5-dihydro-5-oxo-7-phcnyl-8-(phenylsulfonyl)tetrazolo[ 1,5- pyridine-6-carboxy late <2000J(P1)3686>. At the same time, the unexpected azido-tetrazolo tautomerization and reversible tetrazolo transformation of 3,6-diazido-l,2,4,5-tetrazine are remarkable compared to all other polyazido heteroaromatic high-nitrogen C-N compounds <2005JA12537>. [Pg.374]

Unexpected azido-tetrazolo tautomerizations and irreversible tetrazolo transformation have been studied in a report dealing with 3,6-diazido-l,2,4,5-tetrazine (DiAT) for which an improved synthesis pathway is also provided. DiAT undergoes azido-tetrazolo equilibria in CD3OD, (CD3)2C0 and CD3CN and transforms to tetrazolo isomer 53 in DMSO. The... [Pg.360]

Other organic molecules with a very high nitrogen content have been synthesized, e.g. 3,6-diazido-l,2,4,5-tetrazine, 22 ... [Pg.158]


See other pages where Diazido-l,2,4,5-tetrazines is mentioned: [Pg.417]    [Pg.2457]    [Pg.153]    [Pg.417]    [Pg.2457]    [Pg.153]   
See also in sourсe #XX -- [ Pg.417 ]




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1.1- diazido

3.6- Diazido-l,2,4,5-tetrazine

Diazido-1,2,4,5-tetrazines

Tetrazines

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