Detectors multiplexed

As in all Fourier transform methods in spectroscopy, the FTIR spectrometer benefits greatly from the multiplex, or Fellgett, advantage of detecting a broad band of radiation (a wide wavenumber range) all the time. By comparison, a spectrometer that disperses the radiation with a prism or diffraction grating detects, at any instant, only that narrow band of radiation that the orientation of the prism or grating allows to fall on the detector, as in the type of infrared spectrometer described in Section 3.6. 

A more recent, and superior, type of detector, which also benefits from the multiplex advantage, is the charge-coupled device (CCD). The CCD, as used for spectroscopy, has been developed from the CCD detector used in a camcorder. 

Acquisition times commonly vary from seconds to minutes, often with negligible time between acquisitions, even when measuring multiple locations simultaneously (multiplexing). The dedication of different areas on the charge coupled device (CCD) detector to each measurement point makes this possible. The detectors used for MIR and NIR instruments cannot be multiplexed in the same fashion and must measure multiple samples sequentially. 

Figure 24.2 Schematic diagram of the setup used to measure and control H2O concentration and gas temperature in the combustion region (in situ) of a forced 5-kilowatt combustor at Stanford University 1 — steel duct 2 — quartz duct 3 — A1 duct 4 — multiplexed beam 5 — tunable diode lasers 6 — data acquisition and control computer 7 — control signals 8 — primary air driver Aair sin(27r/of) 9 — fuel drivers Afuei sin(27r/of-f dfuei) 10 — demultiplexing box 11 — Si detector (ND filter) and 12 — laser beam...

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