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Desulfurization, deoxy sugars prepared

More recently, Wolfrom and Foster found that the d and l enantio-morphs of methyl 3,4-0-isopropylidene-2-0-[(methylthio)thiocarbonyl]-/3-arabinop3Tanoside rearrange, on pyrolysis, to the appropriate 2-methyl-thio)carbonyl] esters. The reductive desulfurization of methyl 3,4-0-isopropylidene-2- S - [(methylthio)carbonylj - 2 - thio -/3 - d - arabinopyranoside (LXVIII) with Raney nickel, to afford a low yield of methyl 2-deoxy-3,4-0-isopropylidene-/3-D-erj/intramolecular rearrangement to LXVIII, and the relationship of the transformation to the Chugaev reaction was discussed. [Pg.141]


See other pages where Desulfurization, deoxy sugars prepared is mentioned: [Pg.294]    [Pg.125]    [Pg.97]    [Pg.75]    [Pg.171]    [Pg.31]    [Pg.751]    [Pg.323]    [Pg.161]    [Pg.5]   
See also in sourсe #XX -- [ Pg.34 , Pg.141 ]




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