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Deoxy properties

Another microbial polysaccharide-based emulsifier is Hposan, produced by the yeast Candida lipolytica when grown on hydrocarbons (223). Liposan is apparentiy induced by certain water-immiscible hydrocarbons. It is composed of approximately 83% polysaccharide and 17% protein (224). The polysaccharide portion consists of D-glucose, D-galactose, 2-amino-2-deoxy-D-galactose, and D-galacturonic acid. The presence of fatty acyl groups has not been demonstrated the protein portion may confer some hydrophobic properties on the complex. [Pg.298]

Amethopterin — see Folic acid, 4-amino-4-deoxy-10-methyl-Amicetin isolation, 3, 147 Amicibone properties, 7, 545 Amide alkaloids synthesis, 1, 470 Amides... [Pg.514]

Pterin, 4-amino — see Folic acid, 4-amino-4-deoxy-Pterin, 6-amino-structure, 3, 276 Pterin, 7-amino-structure, 3, 276 Pterin, 6-arylthio-reactivity, 3, 299 Pterin, 6-(l-carboxyethoxy)-synthesis, 3, 309 Pterin, 6-carboxy-7-hydroxy-properties, 3, 277 Pterin, 7-carboxy-6-hydroxy-properties, 3, 277 Pterin, 6-chloro-nucleophilic substitution, 3, 292 synthesis, 3, 290... [Pg.755]

Chitosan, having a similar chemical backbone as cellulose, is a linear polymer composed of a partially deacety-lated material of chitin [(l-4)-2-acetamide-2-deoxy-/3-D-glucan]. Grafting copolymer chains onto chitosan can improve some properties of the resulting copolymers [48-50]. Yang et al. [16] reported the grafting reaction of chitosan using the Ce(IV) ion as an initiator, but no detailed mechanism of this initiation has been published so far. [Pg.551]

The deoxyinositols (quercitols, cyclohexanepentols) are useful model compounds which display many of the physical and chemical properties of true deoxy sugars. Although (-b)-proto-quercitol, the best known isomer, was isolated from nature 118 years ago, no synthesis has been reported up until now. The synthesis here described is actually that of the (-)-enantiomer, starting with (-)-inositol however, identical procedures applied to the readily available ( + ) or dl-inositol would give (- -) or DL-proto-quercitol, respectively. The natural occurence of, )-proto-quercitol has... [Pg.49]

Deoxy-sugars. Part IX. Some Properties and Reactions of 2-Deoxy-D-galactose, W. G. Overend, F. Shafizadeh, and M. Stacey,/. Chem. Soc., (1950) 671 -677. [Pg.24]

Amino-sugars and Related Compounds. Part VIII. Some Properties of 2-Deoxy-2-sulphoamino-D-glucose, Heparin, and Related Substances, A. B. Foster, E. F. Martlew, M. Stacey, P. J. M. Taylor, and J. M. Webber, /. Chem. Soc., (1961) 1204-1208. [Pg.34]

This section is completed with a brief review of the synthesis and properties of this epimer (20) of the precursor of thiazole in bacteria. This pentulose is conveniently accessible by an unconventional route (Scheme 19). Methyl 2,3 4,6-di-O-isopropylidene-a-D-mannopyranoside, readily available from methyl ot-D-mannopyranoside, is converted to the ketonic glycoside by butyllithium in 91% yield, following a method first published by Klemer and Rodemeyer43 and scaled up by Horton and Weckerle.44 This was converted by means of lithium hydroxide in a water-ether mixture into 3,5-0-benzylidene-l-deoxy-D-eryf/iro-2-pen-tulose in 55% yield. Hydrolysis to the free pentulose (20) proceeded in 73% yield in aqueous acetic acid. This product was obtained as a syrup with a characteristic absorption band at 1705 cm 1 as a film. Thus, there is a fair proportion of the open-chain ketone under these conditions, as with the D-threo epimer.45... [Pg.288]

Amide derivatives have proved especially useful sugars for study by c.d. spectroscopy. The amide substituent is the same as the chromophore found in proteins, so that its optical properties have been extensively studied both experimentally and theoretically. 2-Acetamido sugars are found in many glycoproteins. The structure of 2-acetamido-2-deoxy-a-D-glucopyranose is given as an example in formula 7. [Pg.94]

The taste properties of the di-O-methylhexopyranosyl derivatives, like those of the corresponding deoxy sugars, are never sweet, and always bitter. As with the deoxy sugars, this is possibly the result of increased lipophilicity of the molecule. In sucrose, however, the presence of two methyl groups on the D-glucopyranosyl or the D-fructofuranosyl group does not seem to cause any marked bitterness (see Table XVIII). [Pg.263]

Stepinski, J., Waddell, C., Stolarski, R., Darzynkiewicz, E., and Rhoads, R. E. (2001). Synthesis and properties of mRNAs containing the novel anti-reverse cap analogues 7-methyl(3 -0-methyl)GpppG and 7-methyl(3 -deoxy)GpppG. RM4 7, 1486-1495. [Pg.259]


See other pages where Deoxy properties is mentioned: [Pg.7]    [Pg.168]    [Pg.214]    [Pg.14]    [Pg.291]    [Pg.83]    [Pg.127]    [Pg.119]    [Pg.234]    [Pg.321]    [Pg.27]    [Pg.108]    [Pg.125]    [Pg.89]    [Pg.108]    [Pg.239]    [Pg.275]    [Pg.67]    [Pg.81]    [Pg.283]   
See also in sourсe #XX -- [ Pg.26 , Pg.279 , Pg.280 , Pg.281 , Pg.282 , Pg.283 , Pg.284 , Pg.285 , Pg.286 , Pg.287 , Pg.288 , Pg.289 , Pg.290 , Pg.291 , Pg.292 , Pg.293 , Pg.294 , Pg.295 ]




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Deoxy derivatives, physical properties

Deoxy derivatives, properties

Properties of 2-amino-2-deoxy sugars and their

Properties of 2-amino-2-deoxy sugars and their derivatives

Sugars deoxy, properties

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