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Dense ceramic membranes disc/flat-sheet membrane

Dense ceramic membranes can be fabricated in three configurations disc/ flat-sheet membrane, tubular membrane and hollow fibre membrane. Their preparation processes are described respectively in details as follows. [Pg.282]

Disc/flat-sheet-shaped membranes are mostly applied in dense ceramic membrane reactors due to the ease of the fabrication process the ceramic material powder is pressed into discs in a stainless steel mould under an isostatic or hydraulic pressure, followed by sintering at a high temperature. Such disc-shaped membranes usually have a thickness of about 1 mm so as... [Pg.282]

Dense ceramic membranes allow oxygen or hydrogen permeation in a dissociated or ionized form other than the conventional molecular diffusion, and thus exhibit extremely high selectivity (up to 100%). They can be incorporated into membrane reactors for a variety of oxidation and dehydrogenation reactions where the membrane functions as either a product extractor or a reactant distributor. Three configurations, that is, disc/flat-sheet, tubular and hollow fibre membranes have been applied in membrane reactors. They exhibit respective advantages/disadvantages in terms of the ease and cost of fabrication, the effective membrane area/volume ratio, and... [Pg.291]

After this chapter. Part 11 is dedicated to zeolite, ceramic and carbon membranes and catalysts used in membrane reactors. In Chapter 6 (Algieri, Comite and Capannelli) the remarkable properties of zeolite membranes are illustrated. Moreover, the key role of zeolite membrane reactors to improve the yield and the selectivity of reactions is particularly emphasised. Furthermore, the possibility of using zeolite membranes as micro-reactors and sensors is also discussed. Chapter 7 (Tan and Li) deals with dense ceramic membrane reactors, which are made from composite oxides usually having perovskite or fluorite structures with appreciable mixed ionic (oxygen ion and/or proton) and electronic conductivity. This chapter mainly describes the principles of various configurations (disc/flat-sheet, tubular and hollow fibre membranes) of dense ceramic membrane reactors and the... [Pg.712]


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