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Dendrimers orthogonal growth

Scheme 13.5 Accelerated orthogonal growth of dendrimers, using the AB2... Scheme 13.5 Accelerated orthogonal growth of dendrimers, using the AB2...
Table 33.1 Overall view of current dendrimers constructed via the orthogonal growth approach. [Pg.1038]

The other accelerated approach for dendrimer synthesis, the orthogonal approach, involves convergent growth with two different monomers. The monomers, an AB2 and a CD2 must be carefully selected such that the focal functionalities of each individual monomer will only react with the periphery of the other monomer (B couples only with C and D only with A) thus removing the need for activation reactions. As... [Pg.66]

Scheme 30.19 The rapid synthesis of a sixth-generation dendrimer using an orthogonal AB2 — CD2 divergent growth approach employing both thiol-ene and CuAAC click coupling reactions, (i) Thiol-ene coupling (ii) CuAAC (iii) Thiol-ene coupling (iv) CuAAC (v) Thiol-ene coupling (vi) CuAAC. Reproduced with permission from Ref [133] 2010, American Chemical Society. Scheme 30.19 The rapid synthesis of a sixth-generation dendrimer using an orthogonal AB2 — CD2 divergent growth approach employing both thiol-ene and CuAAC click coupling reactions, (i) Thiol-ene coupling (ii) CuAAC (iii) Thiol-ene coupling (iv) CuAAC (v) Thiol-ene coupling (vi) CuAAC. Reproduced with permission from Ref [133] 2010, American Chemical Society.
Fig. 28. Cartoon of the AB2 monomer with the amphiphilic groups on the orthogonal plane, the dendrimer growth, and its conformation in a hydrophilic solvent is represented. Fig. 28. Cartoon of the AB2 monomer with the amphiphilic groups on the orthogonal plane, the dendrimer growth, and its conformation in a hydrophilic solvent is represented.
See other pages where Dendrimers orthogonal growth is mentioned: [Pg.1036]    [Pg.1036]    [Pg.1036]    [Pg.1037]    [Pg.1052]    [Pg.128]    [Pg.289]    [Pg.92]    [Pg.102]    [Pg.104]    [Pg.105]    [Pg.5]    [Pg.64]    [Pg.65]    [Pg.94]    [Pg.945]    [Pg.947]    [Pg.1044]    [Pg.1046]    [Pg.1051]    [Pg.122]    [Pg.124]    [Pg.124]    [Pg.423]    [Pg.291]    [Pg.4878]   
See also in sourсe #XX -- [ Pg.1036 ]



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Dendrimer growth

Dendrimers growth

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