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Dendrigraft arborescent -poly

DENDRIGRAFT (ARBORESCENT)-POLY(STYRENE)-GRAFT-POLY(ISOPRENE) COPOLYMERS... [Pg.221]

The solution properties of dendrigraft polybutadienes are, as in the previous cases discussed, consistent with a hard sphere morphology. The intrinsic viscosity of arborescent-poly(butadienes) levels off for the G1 and G2 polymers. Additionally, the ratio of the radius of gyration in solution (Rg) to the hydrodynamic radius (Rb) of the molecules decreases from RJRb = 1.4 to 0.8 from G1 to G2. For linear polymer chains with a coiled conformation in solution, a ratio RJRb = 1.48-1.50 is expected. For rigid spheres, in comparison, a limiting value RJRb = 0.775 is predicted. [Pg.220]


See other pages where Dendrigraft arborescent -poly is mentioned: [Pg.219]    [Pg.219]    [Pg.219]    [Pg.221]    [Pg.221]    [Pg.35]    [Pg.336]    [Pg.228]    [Pg.232]   
See also in sourсe #XX -- [ Pg.224 ]




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