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Degrees of forming

BS 6536 1985 refers to four grades of carbon steel strip coated with Al-Si alloys containing 5-11 wt.% Si. The availability of the steel grades allows account to be taken of the type and degree of forming which is to be applied to the coated steel. Various coating masses are supplied in the range 40-180 g/m which may be additionally protected by a chromate passivation treatment. [Pg.477]

Additionally, different chemical modifications e.g., isomer, salt, inclusion compound, etc., vary in their photosensitivity. It is a common practice in modern drug development to prepare several different modifications of a drug and identify that modification with the most suitable properties, mainly relating to bioavailability. However, the photosensitivity of these different forms may vary markedly, even to the degree of forming different photodegradation products (9). [Pg.327]

To discuss the earlydate and loose/tight featiues of the TSs, degrees of forming and breaking of bonds (n ) have been calculated according to (Eq. 10.1)... [Pg.298]

It has been shown [41, 42] that partial donation of the 7r-electrons from alkene to an empty a-orbital of the metal weakens the 7r-bond of the unsaturated hydrocarbon and therefore lowers it energy, which makes electrons easier accepted from a back-donating d-orbital of the metal atom. Transfer of electrons from the metal d-orbital to the antibonding tt orbital increases the energy of the latter. As the consequence the degree of forming of metal-alkene bond should be reflected in HOMO-LUMO... [Pg.36]

CHR) , formed, e g. from the reaction of diazomethane and alcohols or hydroxylamine derivatives in the presence of boron compounds or with metal compounds. Poly-methylene is formally the same as polyethene and the properties of the various polymers depend upon the degree of polymerization and the stereochemistry. [Pg.320]

The tendency for a solvent to form deposits by polymerization of impurities such as olefins is measured by the test for potential gums . Olefin content can also be represented by the bromine index , which is a measure of the degree of unsaturation (see paragraph 3.4.1). [Pg.274]

Calculate A52 at = 0.1 for argon at 77 K that forms a weak adsorption bond with the adsorbent, having three vibrational degrees of freedom. [Pg.672]

We further make the following tentative conjecture (probably valid only under restricted circumstances, e.g., minimal coupling between degrees of freedom) In quantum field theories, too, the YM residual fields, A and F, arise because the particle states are truncated (e.g., the proton-neutron multiplet is an isotopic doublet, without consideration of excited states). Then, it is within the truncated set that the residual fields reinstate the neglected part of the interaction. If all states were considered, then eigenstates of the form shown in Eq. (90) would be exact and there would be no need for the residual interaction negotiated by A and F. [Pg.158]

A conical intersection needs at least two nuclear degrees of freedom to form. In a ID system states of different symmetry will cross as Wy = 0 for i j and so when Wu = 0 the surfaces are degenerate. There is, however, no coupling between the states. States of the same symmetry in contrast cannot cross, as both Wij and Wu are nonzero and so the square root in Eq. (68) is always nonzero. This is the basis of the well-known non-crossing rule. [Pg.286]

Explicit forms of the coefficients Tt and A depend on the coordinate system employed, the level of approximation applied, and so on. They can be chosen, for example, such that a part of the coupling with other degrees of freedom (typically stretching vibrations) is accounted for. In the space-fixed coordinate system at the infinitesimal bending vibrations, Tt + 7 reduces to the kinetic energy operator of a two-dimensional (2D) isotropic haiinonic oscillator. [Pg.480]

The obvious way to form a similarity between the Wigner rotation matrix and the adiabatic-to-diabatic transformation mabix defined in Eqs. (28) is to consider the (unbreakable) multidegeneracy case that is based, just like Wigner rotation matrix, on a single axis of rotation. For this sake, we consider the particular set of T matrices as defined in Eq. (51) and derive the relevant adiabatic-to-diabatic transfonnation matrices. In what follows, the degree of similarity between the two types of matrices will be presented for three special cases, namely, the two-state case which in Wigner s notation is the case, j =, the tri-state case (i.e.,7 = 1) and the tetra-state case (i.e.,7 = ). [Pg.686]

If a dilute acid is added to this solution, a white gelatinous precipitate of the hydrated tin(IV) oxide is obtained. It was once thought that this was an acid and several formulae were suggested. However, it now seems likely that all these are different forms of the hydrated oxide, the differences arising from differences in particle size and degree of hydration. When some varieties of the hydrated tin(IV) oxide dissolve in hydrochloric acid, this is really a breaking up of the particles to form a colloidal solution—a phenomenon known as peptisation. [Pg.193]

A mapping is said to be symplectic or canonical if it preserves the differential form dp A dq which defines the symplectic structure in the phase space. Differential forms provide a geometric interpretation of symplectic-ness in terms of conservation of areas which follows from Liouville s theorem [14]. In one-degree-of-freedom example symplecticness is the preservation of oriented area. An example is the harmonic oscillator where the t-flow is just a rigid rotation and the area is preserved. The area-preserving character of the solution operator holds only for Hamiltonian systems. In more then one-degree-of-freedom examples the preservation of area is symplecticness rather than preservation of volume [5]. [Pg.335]

We will assume in this article that the system is time-reversible, so T(p) = T —p). Dichotomic Hamiltonians arise from elementary particle models, the simplest nontrivial class of conservative systems. Moreover, even seemingly more complex systems can usually be written in the dichotomic form through change of variables or introduction of additional degrees of freedom. [Pg.353]

Spanned by tbc atoms 4, 2, and 1, and 2, 1, and 3 (tlic ry-planc), Except of the first three atoms, each atom is described by a set of three internal coordinates a distance from a previously defined atom, the bond angle formed by the atom with two previous atoms, and the torsion angle of the atom with three previous atoms. A total of 3/V - 6 internal coordinates, where N is the number of atoms in the molecule, is required to represent a chemical structure properly in 3D space. The number (,3N - 6) of internal coordinates also corresponds to the number of degrees of freedom of the molecule. [Pg.94]

Materials that contain defects and impurities can exhibit some of the most scientifically interesting and economically important phenomena known. The nature of disorder in solids is a vast subject and so our discussion will necessarily be limited. The smallest degree of disorder that can be introduced into a perfect crystal is a point defect. Three common types of point defect are vacancies, interstitials and substitutionals. Vacancies form when an atom is missing from its expected lattice site. A common example is the Schottky defect, which is typically formed when one cation and one anion are removed from fhe bulk and placed on the surface. Schottky defects are common in the alkali halides. Interstitials are due to the presence of an atom in a location that is usually unoccupied. A... [Pg.638]

Absolute ethyl alcohol. Ethyl alcohol of a high degree of purity is frequently required in preparative organic chemistry. For some purposes alcohol of ca. 99 -5 per cent, purity is satisfactory this grade may be purchased (the absolute alcohol of commerce), or it may be conveniently prepared by the dehydration of rectified spirit with quicklime. Rectified spirit is the constant boiling point mixture which ethyl alcohol forms with water, and usually contains 95 6 per cent, of alcohol by weight. Wherever the term rectified spirit is used in this book, approximately 95 per cent, ethyl alcohol is to be understood. [Pg.166]


See other pages where Degrees of forming is mentioned: [Pg.233]    [Pg.311]    [Pg.625]    [Pg.63]    [Pg.95]    [Pg.240]    [Pg.241]    [Pg.242]    [Pg.233]    [Pg.311]    [Pg.625]    [Pg.63]    [Pg.95]    [Pg.240]    [Pg.241]    [Pg.242]    [Pg.158]    [Pg.181]    [Pg.240]    [Pg.257]    [Pg.359]    [Pg.580]    [Pg.283]    [Pg.239]    [Pg.251]    [Pg.457]    [Pg.508]    [Pg.557]    [Pg.770]    [Pg.190]    [Pg.270]    [Pg.119]    [Pg.437]    [Pg.98]    [Pg.411]    [Pg.417]    [Pg.532]    [Pg.678]    [Pg.21]    [Pg.129]   
See also in sourсe #XX -- [ Pg.214 ]




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