Decalactone, butter aroma

By using aroma extract dilution analysis (AEDA) of the volatile fractions of fresh and stored butter oil, Widder et al. (29) determined diacetyl, butanoic acid, 8-octalactone, skatole, 8-decalactone, cw-6-dodeceno-8-decalactone, l-octen-3-one, and l-hexen-3-one as potent contributors to the flavor of butter oil. The concentration of l-octen-3-one, trani-2-nonenal, and i-l,5-octadien-3-one increased during the storage of the butter oil at room temperature. 

Table 5 shows the sensory evaluation by Schieberle et al. (30) of the different kinds of butter, namely, Irish sour cream (ISC), cultured butter (CB), sour cream (SC), sweet cream (SwC), and farmer sour cream (ESC). It revealed ISC butter and ESC butter with the highest overall odor intensities. Table 5 shows that 19 odor-active compounds were detected by aroma extract dilution analysis (AEDA) in a distillate of the ISC butter. The highest flavor dilution (ED) factors have been found for 5-decalactone, skatole, i-6-dodeceno-y-lactone, and diacetyl followed by trany-2-nonenal, cw,c -3,6-nonadienal, c/i-2-nonenal, and l-octen-3-one. 

In the AEDA of UHT milk (Table 10.38), 5-decalactone, which contributes to the aroma of butter (Table 10.40) as well as unripened and ripened cheese (cf. 10.3.5), is the predominant aroma substance. Apart from other lactones, 2-acetyl-l-pyrroline, methional, 2-acetyl-2-thio-azoline and 4,5-epoxy-2-decenal are among the identified aroma substances. 

The aroma profile of unripened cheese, e. g.. Mozzarella, consists of butter-like, sweetish, salty and sour notes produced by 1,5-decalactone, NaCl and lactic acid. The characteristic odor and taste of the type of cheese are formed during ripening, whereby the composition of the microflora and the storage conditions (temperature, air humidity, time) have the greatest influence. For a soft cheese (Camembert) and a hard cheese (Emmentaler), the compounds mainly responsible for the odor and taste in the ripened product will be discussed here. 

The most aroma-active compounds in fresh sour cream butter were elucidated as the character impact compound diacetyl, with supporting roles from 5-decalactone, (Z)-6-dodeceno-y-lactone, and butyric acid (81). 

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