Debye-Hueckel theory

T. Kennedy. Debye-Hueckel theory for charge symmetric Coulomb systems. Commun Math Phys 92 269-294, 1983. 

Lee, B.P., and Fisher, M.E. Density fluctuations in an electrolyte from generalized Debye-Hueckel theory. Phys. Rev. Lett., 1996, 76, p. 2906-9. 

Basic equations for almost every subfield of electrochemistry from first principles, referring at all times to the soundest and most recent theories and results unusually useful as text or as reference. Covers coulometers and Faraday s Law, electrolytic conductance, the Debye-Hueckel method for the theoretical calculation of activity coefficients, concentration cells, standard electrode potentials, thermodynamic ionization constants, pH, potentiometric titrations, irreversible phenomena. Planck s equation, and much more, a indices. Appendix. 585-item bibliography. 197 figures. 94 tables, ii 4. 478pp. 5-% x 8. ... 

While polyelectrolyte behavior is generally not within the remit of this work, Stellwagen, et a/. s use of capillary electrophoresis to examine a fundamental physico-chemical issue is worthy of note(49). Their interest was a vexing question, namely whether or not zwitterions contribute to the ionic strength / of a solution. Many would assert that the theoretical studies of Kirkwood are substantially definitive, but some doubts remain(50,51). Stellwagen, etal. noted that the Debye-Hueckel-Onsager electrophoretic theory requires pi [Pg.57]

Debye and Hueckel s work is historically important to soil chemistry because their derivation was similar to that of Guoy and Chapman, published independently about 1910, who tried to predict the ion distribution in the aqueous solution around a charged surface such as a soil particle. Although the Guoy-Chapman theory and its... 

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