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Cyclopropane trick

Therefore acceptor cyclopropanes 1 will be ring opened by nucleophiles N to provide products like 2 (homo Michael addition) as depicted in Eq. 1. On the other hand, electrophiles E+ cleave donor activated cyclopropanes 3 affording adducts 4 or 5 which demonstrates that the cyclopropane serves as a homoenolate equivalent in this sequence (Eq. 2). Seebach consequently classified these methods as umpolung with the cyclopropane trick 4. ... [Pg.75]


See other pages where Cyclopropane trick is mentioned: [Pg.5]    [Pg.1]    [Pg.903]    [Pg.379]    [Pg.903]    [Pg.5]    [Pg.1]    [Pg.903]    [Pg.379]    [Pg.903]   
See also in sourсe #XX -- [ Pg.378 ]




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