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Cyclopentane, thermodynamic properties

Yoneda, Y. (1979). An Estimation of the Thermodynamic Properties of Organic Compounds in the Ideal Gas State. I. Acyclic Compounds and Cyclic Compounds with a Ring of Cyclopentane, Cyclohexane, Benzene or Naphthalene. Bull.Chem.Soc.Jap., 52,1297-1314. [Pg.665]

Liquid-liquid equilibrium data of polystyrene in cyclopentane and cyclohexane Data extract from Landolt-Bornstein VIII/6D3 Polymers, Polymer Solutions, Physical Properties and their Relations I (Thermodynamic Properties Equilibria of Ternary Polymer Solutions) ... [Pg.254]

Table 14. Effect of Dimethyl Substitution on the Equilibrium Constants and Thermodynamic Properties for the Cyclization of Cyclopentane and Cyclohexane... Table 14. Effect of Dimethyl Substitution on the Equilibrium Constants and Thermodynamic Properties for the Cyclization of Cyclopentane and Cyclohexane...
Such assignments are in error, however, even though one of them is based on a normal-co-ordinate calculation, and are quite unable, with or without a contribution of pseudo-rotation, to reproduce the measured heat capacity. The most accurate values of the measured thermodynamic properties require, for agreement within 0.1%, that /, = 10.59 x 10 gem a small contribution of anharmonicity was treated by equations (15). A subsequent molecular vibrational analysis led to some revision of the vibrational assignment, but excellent agreement with the measured heat capacity values is still obtained from it-provided the contribution of pseudo-rotation is included. The details of the selection rules for cyclopentane have been discussed. ... [Pg.305]

Pseudo-rotation.— The concept of pseudo-rotation was introduced by Kilpatrick, Pitzer, and Spitzer to account for the thermodynamic and spectroscopic properties of cyclopentane. Although the basis of the... [Pg.303]


See other pages where Cyclopentane, thermodynamic properties is mentioned: [Pg.1205]    [Pg.395]    [Pg.9]    [Pg.869]   
See also in sourсe #XX -- [ Pg.275 ]

See also in sourсe #XX -- [ Pg.275 ]




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