Cyclopentane Glycol

In the case of the cyclopentane oxirane 424, fluorination [KHFj, Me0(CH2)20H] proceeded to give preferably one fluoroalcohol, 426 (61%) over the isomeric one, 425 (7%), possibly by the influence of the benzyloxy-methyl group. Similarly (KHF2, ethylene glycol, 160°), another oxirane, 427, was converted into 428 (30%). 2-C-(Fluoromethyl)-/ T6>-inositol (429)... [Pg.165]

Cyclohexanol, Cyclopentane, Cyclopentene, 1,2-Dichloroethane, Diethyl phthalate, 1,4-Dioxane, Ethephon. Ethylamine, Ethylene dibromide, Ethylenimine, p-Propiolactone, Tetraethyl pyrophosphate, TCDD, 1,1,1-Trichloroethane, Trichloroethylene, Vinyl chloride Ethylene chlorohydrin, see Bis(2-chloroethyl) ether Ethylenediamine, see Ethylene thiourea. Maneb Ethylene glycol, see Bis(2-chloroethyl) ether, 1,2-Dichloroethane, Ethylene chlorohydrin. Ethylene dibromide... [Pg.1529]

Sodium toluene dispersion of, 55, 65 Sodium p-toluenesulfinate, 57, 103 Spiro[4 n] alkenones, 58, 62 Spiro[cyclopentane-l,l -indene] 55, 94 Squalene, 56, 116 Squalene, 2,3-epoxy, 56, 116 Stannic chloride, 56, 97 Steroids synthesis, 58, 85 E Stilbene, 55, 115,58, 73 z-Stilbene, 58, 133 Styrene, 56, 35,58, 43 Styrene glycol, 55, 116 Styrene glycol dimesylate, 55, 116 Succinic acid, 58, 85 Succinic anhydride, 58, 85 Sucunimide, 56, 50, 58, 126 Succimmide, Vbromo, 55, 28, 56, 49 SULFIDE CONTRACTION, 55, 127 Sulfide, dimethyl-, 56, 37 SULFIDE SYNTHESIS, 58, 143,58, 138 SULFIDE SYNTHESIS ALKYL ARYL SULFIDES, 58, 143 SULFIDE SYNTHFSIS DIALKYL SULFIDES, 58, 143 SULFIDE SYNTHESIS UNSYMMETRI-CAL DIALKYL DISULFIDES, 58, 147 SULFONYL CYANIDES, 57, 88 Sulfur tetrafluoride, 57, 51... [Pg.192]

Because glycol formation involves a back-side attack on a protonated epoxide, the result is anti orientation of the hydroxyl groups on the double bond. For example, when 1,2-epoxycyclopentane ( cyclopentene oxide ) is treated with dilute mineral acid, the product is pure trans-cyclopentane- 1,2-diol. [Pg.363]

For many purposes, such as formation of cyclic derivatives of glycols, vicinal cis groups attached to the cyclopentane ring may be considered to... [Pg.12]

Cyclobutane-l,l-dicarboxylic i cyclopentane-1,l-dicarboxylic j cyclohexane-1,1-dicarboxylic f melt, H2SO4, H3PO4, collidine and diethylene glycol 485 212 195... [Pg.469]

Stereoisomerism of this same sort should be possible for compounds other than glycols, and for rings other than cyclopentane. Some examples of isomers that have been isolated are ... [Pg.302]

This result contrasts with that from cyclopentanone tosylhydrazone, which yielded cyclopentane (94%) as the major product,and with the cationic decomposition of the sodium salt of cyclobutanone tosylhydrazone in ethylene glycol which gave an 86% yield of a mixture of bicyclo[1.1.0]butane 41 (60%), cyclobutene (12%) and methylenecyclopropane (6%). Likewise, deamination of cyclobutylamine hydrochloride with amyl nitrite leads in low yield (13%) to methylenecyclopropane (56%) along with cyclobutene (40%). ... [Pg.1016]

Simple organic compounds o-tcrphenyl, toluene, 3-mcthyl hexane, 2,3-dimethyl ketone, diethyl ether, isobutyl bromide, ethylene glycol, methyl alcohol, ethyl alcohol, glycerol, glucose. As droplets only m-xylene, cyclopentane, n-heptane, methylene chloride. [Pg.22]

Tris (ethylenediamine) cadmium dihydroxide Zinc chloride solvent, cellulose acetate Acetylacetone Benzaldehyde Benzyl acetate Butyl formate Cyclohexanone Cyclopentane Diacetone alcohol Diethyl phthalate Ethylbenzene Ethylene glycol acetate... [Pg.5687]

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