Cyclopentadienyl titanium halide chemistry and related topics

The reduction of the complexes (7r-C5H5)MCl2, where M = Ti or Zr, with sodium borohydride gives the novel deep blue paramagnetic bridging borohydride derivative, 4.21 [245]. It is interesting that magnetic 

Both halides and oxyhalides may be prepared from the tetracarbonyl, 4.23 [250, 251]. The vanadium(IIl) chloride, 4.24, is prepared by the redistri- 

Few studies have been made on the complexes (7r-CjHs)2MX3, where M = Nb or Ta, but it appears that they are readily hydrolysed [117] by 

The chromium halide and oxide complexes have been prepared by novel 

The abstraction of a hydride ion from neutral cyclohexadiene-metal complexes by triphenylme yl (trityl), tetrafluoroborate. 

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