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Cyclopentadienyl ligand oxygen sensitivity

With 1,1-difluorocyclopropabenzene and a range of nickel(O) complexes, nickelabicy-clobutanes 118 (84—93%) are formed by loss of olefin or phosphane ligands and addition of the nickel atom across the bridge bond (Scheme 20)256-266. The products appear to be stable at ambient temperatures but are oxygen sensitive the majority revert to cycloproparene in solution even below -20 °C. With (j -allyl)( s-cyclopentadienyl(palladium in the... [Pg.747]

Similar to the chemistry described in the preceding section, some (arsanylalkyl)cyclopentadienyl complexes were reported. Arsane ligands for transition metals in contrast to phosphanes have the advantage that they are not sensitive to oxidation by oxygen. ... [Pg.28]

See other pages where Cyclopentadienyl ligand oxygen sensitivity is mentioned: [Pg.4238]    [Pg.315]    [Pg.315]    [Pg.238]    [Pg.158]    [Pg.10]    [Pg.158]    [Pg.707]   
See also in sourсe #XX -- [ Pg.130 , Pg.131 ]

See also in sourсe #XX -- [ Pg.130 , Pg.131 ]



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Oxygen ligands

Oxygen sensitivity

Oxygen-sensitive

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