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Cyclooctyl fluoride

Cyclooctadiene-1,5, 23, 62, 445 Cyclooctane-1,2-diol, 384 Cyclooctane-1,5-diol, 64 Cyclooctanol, 183 Cyclooctatetraene, 23 Cyclooctatetraene epoxide, 306, 519 Cyclooctatetraeneiron tricarbonyl, 567 Cyclooctene, 23, 183, 445 Cyclooctene oxide, 334 Cyclooctyl fluoride, 183 Cyclopentadiene, 123, 291 Cyclopentadienone, 454 iT-CycIopentadienylcobalt dicarbonyl, 153-154... [Pg.371]

Diethylaminosulphur trifluroide converts cyclo-octanol into a mixture of cyclooctyl fluoride (70%) and ds-cyclo-octene (30%). Kinetic data suggests that there is considerable C—Br bond breaking in the transition state for abstraction of bromine from cycloalkyl bromides by phenyl radicals, and that anchimeric assistance by an adjacent bromine atom to bromine abstraction depends upon the accessibility of a trans-periplanar alignment of leaving and neighbouring groups. ... [Pg.286]

This dichotomy is quite evident in the reaction of cydooctane with nitronium trifluoroacetate. The products obtained were cyclooctyl triflu-oroacetate, cyclooctyl nitrate and nitrocydooctane. Conversion of adaman-tane to 1-fluoroadamantane in 95% 3ueld on reaction with nitronium tetrafluoroborate in pyridine polyhydrogen fluoride indicates that formation of adamantyl cation by formal hydride abstraction is a significant alternative to the nitration-protodenitration pathway. [Pg.173]

See other pages where Cyclooctyl fluoride is mentioned: [Pg.181]    [Pg.183]    [Pg.479]    [Pg.181]    [Pg.183]    [Pg.479]   
See also in sourсe #XX -- [ Pg.57 , Pg.73 ]

See also in sourсe #XX -- [ Pg.57 , Pg.73 ]

See also in sourсe #XX -- [ Pg.57 , Pg.73 ]

See also in sourсe #XX -- [ Pg.183 ]



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