Cyclooctatetraeneiron tricarbonyl

The mass spectrum of cyclooctatetraeneiron tricarbonyl shows stepwise loss of the three carbonyl groups from the molecular ion, followed by elimination of acetylene giving C6H6Fe+, and further breakdown gives Fe+ (119). The mass spectra of two substituted cyclooctatetraene complexes (see Table VIII) show the molecular ion and stepwise loss of the carbonyl groups (83). 

M. D. Rausch, and G. N. Schrauzer, Cyclooctatetraeneiron Tricarbonyl and Cycloocta-tetraenediiron Hexacarbonyl, Chem. Ind. 1959, 957-958. 

Cycloaddition (5,647-648). The first step in a synthesis of (+)-2,3-dihydro-triquinacenone-2 (5) involves addition of TCNE to cyclooctatetraeneiron tricarbonyl (1) in a 1,3-bonding scheme. The yield is surprisingly high (96%). The iron atom is then extruded by oxidation with ceric ammonium nitrate (4, 72)... 

Cyclooctadiene-1,5, 23, 62, 445 Cyclooctane-1,2-diol, 384 Cyclooctane-1,5-diol, 64 Cyclooctanol, 183 Cyclooctatetraene, 23 Cyclooctatetraene epoxide, 306, 519 Cyclooctatetraeneiron tricarbonyl, 567 Cyclooctene, 23, 183, 445 Cyclooctene oxide, 334 Cyclooctyl fluoride, 183 Cyclopentadiene, 123, 291 Cyclopentadienone, 454 iT-CycIopentadienylcobalt dicarbonyl, 153-154... 

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