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Cyclooctadienes transannular hydride shifts

Transannular hydride shifts, first detected by Cope and coworkers in solvolyses of cyclooctene oxide, have subsequently been found in a number of related systems, e.g. cyclooctadiene monoepoxides, CA o-bicyclo[3.3.1 ]non-2-ene epoxide and l-oxaspiro[2.6]nonane. In general these reactions do not involve skeletal rearrangements, and they will not be discussed in detail. [Pg.735]


See also in sourсe #XX -- [ Pg.3 , Pg.735 ]

See also in sourсe #XX -- [ Pg.735 ]

See also in sourсe #XX -- [ Pg.3 , Pg.735 ]




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1.3- Cyclooctadien

Cyclooctadienes

Cyclooctadienes 1.3- Cyclooctadiene

Hydride shift

Transannular

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