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Cyclohexanone methoxylation

Similar syntheses of arylated 1,3-dioxo-cyclohexanone derivatives also lead to arylated phenols. The enolic methoxyl group of the enolketone is removed using lithiumaluminiumhydride. Acetone cyanhydrin transforms the enolic methoxyl group into a cyano group. Arylated cyano phenols are also available109) by this route ... [Pg.116]

A typical and very recent example is given in Ref. 8. The methoxylation of cyclohexanone is carried out in methanol with potassium iodide as electrolyte. One distillation step and one filtration follow the electrolysis. [Pg.1261]

Electrochemical a-acetoxylation or a-methoxylation of cyclohexanones, followed by reduction or a Grignard reaction and finally acid-catalysed dehydration has been found to provide a convenient method for carbonyl 1,2-transposition. Thus 1-tetralone is converted into 2-tetraIone etc. [Pg.162]

See other pages where Cyclohexanone methoxylation is mentioned: [Pg.442]    [Pg.431]    [Pg.479]    [Pg.1295]    [Pg.91]    [Pg.339]    [Pg.305]    [Pg.289]    [Pg.289]   
See also in sourсe #XX -- [ Pg.1261 ]



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Methoxylations

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