Cyclohexanes hexafluoro

At a given temperature, the cis-57/trans-55 ratio is independent of the olefin concentration over a range of 150-fold dilution with cyclohexane. Hexafluoro-benzene as diluent results in a more stereospecific reaction... 

Trifluoro-3,5,5-trimethylhexane (4,4,4-Trifluorobutyl) cyclohexane 1,1,1,10,10,10-Hexafluorodecane 1,1,1,6,6,6-Hexafluoro-3-hexene -Bis(trifluoromethyl)benzene 2,4-Bis(trifluoromethyl)chlorobenzene -Trifluoromethylnitrobenzene... 

Figure 1. Chemical structures of used model molecules a) Cycloaliphatic epoxy resin (Araldite CY179), b) Methylcyclohexyl cyclohexanecarboxylate (Ester), c) Dicyclohexyl ketone d) cyclohexane oxide e) Bisphenol F epoxy resin (Epon 862), f) Bisphenol A epoxy resin (DER 331), g) Ethyl acetate, h) acetone, i) Phenol, j) 1,1,1,3,3,3 Hexafluoro-2-propanol (HFIP)...

Cyclodimerization and Cycloaddition. Tris(l,l,l,3,3,3-hexafluoro-2-propyl)phosphite serves as a ligand in Ni-catalyzed cyclodimerization reactions as well as Rh- or Ni-catalyzed [4-f2] cycloaddition processes. The first example is Ni-catalyzed dimerization of isoprene with tris(l,l,l,3,3,3-hexafluoro-2-propyl) phosphite ligand. The main product is l,4-dimethyl-4-vinyl-cyclohexane (eq 4). 

The photochemical decomposition of 2f/-hexafluoropropyl azide into nitrogen and 3 -hexafluoro-2-azabut-l-ene has been suggested to involve the formation and subsequent rearrangement of 2j7>hexafluoropropylnitrene, since in the presence of cyclohexane, methylcyclohexane or cyclohexene C—H insertion products are formed, e.g. 

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