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Cyclohexane-1,3-dione acylation

The acylation of cyclohexane-1,3-dione 1358 with pyrrole-2-carbonyl chloride 1357 (X = C1) proceeded normally and gave the O-acylated product 1359 (Scheme 259) <1996TL1007>. [Pg.233]

A very simple triketone has proven useful for treating the rare genetic disease tyrosinemia. The drug alternately known as nitisinone (30) or orfadin actually hears a very close relation to a pesticide. The analogue in which methylsulfonyl replaces the trifluoromethyl group, mesotrione, is an important corn herbicide. Acylation of cyclohexan-l,3-dione, shown as an enol (28) with acid chloride (29), leads in a single step to 30. ... [Pg.47]

See other pages where Cyclohexane-1,3-dione acylation is mentioned: [Pg.323]    [Pg.452]    [Pg.452]    [Pg.361]    [Pg.452]    [Pg.835]    [Pg.835]    [Pg.270]    [Pg.279]    [Pg.774]    [Pg.182]    [Pg.74]    [Pg.413]    [Pg.247]    [Pg.415]    [Pg.97]    [Pg.835]   
See also in sourсe #XX -- [ Pg.835 ]

See also in sourсe #XX -- [ Pg.835 ]



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