Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Cyanosilane

Cyano compounds liquid crystals, 12, 278 in silver(III) complexes, 2, 241 Cyanocuprates, with copper, 2, 186 Cyano derivatives, a-arylation, 1, 361 Cyanosilanes, applications, 9, 322 Cyclic acetals, and Grignard reagent reactivity, 9, 53 Cyclic alkenes, asymmetric hydrosilylation, 10, 830 Cyclic alkynes, strained, with platinum, 8, 644 Cyclic allyl boronates, preparation, 9, 196 Cyclic allylic esters, alkylation, 11, 91 Cyclic amides, ring-opening polymerization, via lanthanide catalysis, 4, 145... [Pg.88]

Cyanosilylations of carbon-oxygen and carbon-nitrogen double bonds with cyanosilanes are very important synthetic reactions since the products, cyanohydrin silyl ethers and a-amino nitriles, serve as synthetic intermediates for a variety of natural products. A number of studies on these subjects have been reported in the last decade however, this review does not deal with carbonyl and imine cyanosilylations due to the availability of recent reviews and limited... [Pg.322]

Cyanosilanes can be isocyanide sources since a tautomeric equilibrium exists between cyanosilanes and the corresponding isocyanides. The equilibrium largely favors the cyano tautomer. The use of such dilute isocyanide donors realizes efficient Ti(n)- and Ni(0)-catalyzed cyclizations of enynes to iminocyclopentenes via metallacyclopentene intermediates (Scheme 19).266,266 266b Treatment of zirconacyclopentanes and -pentenes with Me3SiCN provides zirconocene-imine complexes, which serve for carbon-carbon bond formation with various unsaturated bonds.267... [Pg.323]

A. J. L. Pombeiro, D. L. Hughes, C. J. Pickett, and R. L. Richards, The Aminocarbyne Ligand CNH2 Metal-centred Synthesis from a Cyanosilane, Preparation and X-Ray... [Pg.289]

Carbon-Carbon Bond Formation with Cyanosilanes... [Pg.550]

Jacobsen et al. have reported that peptide Schiff bases and an Al-salen complex are valuable for asymmetric hydrocyanation of imines with TBSCN [660] and TMSCN [661], respectively. It is, however, most likely that HCN arising from these cyanosilanes and adventitious water is the reactive nucleophile. Hoveyda et al. also have used TMSCN as a source of HCN in the hydrocyanation of imines catalyzed by a Ti-peptide Schiff base complex [662],... [Pg.557]

The Ni-catalyzed reaction of 2-bromo-l,6-heptadienes with cyanosilanes affords cyclic and open chain adducts (Scheme 10.245) [669]. TMSCN and El.SiCN are available for this reaction whereas bulky cyanosilanes such as TBSCN and i-PtsSiCN result in sluggish or incomplete reactions leading to predominant formation of fhe open chain adducts. The product ratio is strongly affected by the substitution pattern of fhe substrate. [Pg.558]

Pseudohalide Derivatives of Silicon and Tin.—Dimethyl cyanosilane, Me2Si(CN)H, has been examined by i.r., Raman, and microwave spectroscopy, from which precise structural parameters and the dipole moment have been determined. From the low-frequency vibrational assignment, an upper limit of 2.8kcalmor for the barrier to internal rotation of the methyl groups was deduced. Trimethylcyanosilane forms 1 1 adducts of composition (63) with... [Pg.222]

Quite common too is the treatment of alkyl- or arylhalogenosilanes with silver cyanide to synthesize the corresponding cyanosilanes (equation 252)269. Finally, 521 can also be... [Pg.720]

Near total 1,2- and 1, 3-asymmetric induction was observed in reactions of a- and -alkoxyacyl cyanides respectively, with the tertiary cyanohydrins to obtained being configurationally stable. Secondary cyanohydrins were obtained after addition of cyanosilanes to the acyl cyanides under similar conditions but with only partial asymmetric induction. The potential application of these methods to the synthesis of carbohydrates was noted. [Pg.282]

Numerous silicon organic compounds are efficiently and simply prepared using PTC methodology. Thus the most convenient and economical way of synthesis of trimethyl cyanosilane and other trialkylcyanosilanes, important reagents in organic chemistry, consists in use of liquid-solid PTC (eq. 184). [Pg.1865]

The aminocarbyne ligand CNH2 Metal-centred synthesis from a cyanosilane, preparation and X-ray structure of trans- [ReCl (CNH2) (Ph2PCH2CH2PPh2) 2] BF4 J.C.S. Chem.Commun., (1986), 246-247... [Pg.378]

Cyclohexanone allowed to react with an equimolar amount of trimethylsilyl cyanide in the presence of a trace of zinc iodide product. Y 94%. - The 0X0 compds. may be readily regenerated in dil. aq. acid or base. F. e., also from aldehydes, s. D. A. Evans, L. K. Truesdale, and G. L. Carroll, Chem. Commun. 1973, 55 with AlClg cf. W. Lidy and W. Sundermeyer, B. 106, 587 (1973) f. reactions with cyanosilanes cf. Tetrah. Let. 1973, 1449 preferential protection of carbonyl groups in quinones, f. catalysts, cf. Am. Soc. 95, 5822 (1973). [Pg.502]

Reactions with cyanosilanes a-Siloxynitriles from oxo compds. [Pg.149]


See other pages where Cyanosilane is mentioned: [Pg.372]    [Pg.42]    [Pg.43]    [Pg.322]    [Pg.670]    [Pg.421]    [Pg.220]    [Pg.275]    [Pg.303]    [Pg.490]    [Pg.547]    [Pg.661]    [Pg.276]    [Pg.151]    [Pg.254]    [Pg.259]    [Pg.290]    [Pg.375]   
See also in sourсe #XX -- [ Pg.33 ]




SEARCH



Carbon Bond Formation with Cyanosilanes

Cyanosilanes

Cyanosilanes

Cyanosilanes reactions with

Cyanosilanes trimethylsilyl cyanide

© 2024 chempedia.info