Cyanogenic glycosides linustatin

Selmar, D., Lieberei, R. and Biehl, B. (1988) Mobilization and utilization of cyanogenic glycosides the linustatin pathway. Plant Physiol, 86, 711-6. 

The cyanophoric compounds linamarin (11) (/ )-lotaus-tralin (42), (5)-epilotaustralin (43), linustatin (44), neolinus-tatin (45), and sarmentosin epoxide (46) (probable) are derived from valine and isoleucine (Fig. 16.11). The first two compounds are widespread and probably are found in more plant species than any other cyanogenic glycosides. Linamarin and lotaustralin almost always co-occur. These gluco-sides are most commonly encountered in the Asteraceae, Euphorbiaceae, Fabaceae, and Linaceae. 

Smith, C. R., Jr., D. Weislbder, R. W. Miller, I. S. Palmer, and O. E. Olson, Linustatin and neolinustatin Cyanogenic glycosides of linseed meal that protect animals against selenium toxicity, J. Org. Chem., 45, 507-510 (1980). 

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